column 7 of the hazardous materials table

N6 Battery fluid packaged with electric storage batteries, wet or dry, must conform to the packaging provisions of 173.159 (g) or (h) of this subchapter. Column 7: Special provisions. DOT Specification 57 port-able tanks used for the transport by vessel of Class 3, Packaging Group II materials must conform to the fol-lowing: (1) Minimum design pressure. 11 The hazardous material must be packaged as either a liquid or a solid, as appropriate, depending on its physical form at 55 C (131 F) at atmospheric pressure. N76 For materials of not more than 25 percent active ingredient by weight, packages consisting of inner metal packagings not greater than 250 mL (8 ounces) capacity each, packed in strong outer packagings together with sufficient absorbent material to completely absorb the liquid contents are authorized and need not conform to the requirements of part 178 of this subchapter. 132 This description may only be used for ammonium nitrate-based compound fertilizers. If a fuel cell engine is installed in a vehicle, the vehicle must be described using Vehicle, fuel cell, flammable gas powered or Vehicle, fuel cell, flammable liquid powered, as appropriate. Shipments made in accordance with this Special provision are excepted from the requirements of 173.60(b)(4) of this subchapter. B18 Open steel hoppers or bins are authorized. If one of the components, which can be a pure substance or a mixture, is classed as flammable, the chemical under pressure must be classed as flammable in Division 2.1. (9) A code containing the letter W refers to a special provision that applies only to transportation by water. Large Packagings are authorized for the Packing Group III entries of specific proper shipping names when either special provision IB3 or IB8 is assigned to that entry in the 172.101 Table. The identification number used must be consistent on package markings, shipping papers and emergency response information. A 25 mm (1 inch) woven lining of asbestos or other approved material must be placed between the bolster slabbing and the bottom of the tank. 350 Ammonium bromate, ammonium bromate aqueous solutions, and mixtures of a bromate with an ammonium salt are forbidden for transport. B65 Tank cars constructed before March 16, 2009, must have a test pressure of 34.47 Bar (500 psig) or greater and conform to Class 105A. This may be fulfilled by an additional locking device linked to the activator; (4) Each article must be manufactured in such a way as to prevent hazardous projections of the pressure receptacle or parts of the pressure receptacle; (5) Each pressure receptacle must be manufactured from material which will not fragment upon rupture; (6) The design type of the article must be subjected to a fire test. b. 196 The nitrocellulose must meet the criteria of the Bergmann-Junk test or methyl violet paper test in the UN Manual of Tests and Criteria, Appendix 10 (IBR, see 171.7 of this subchapter). Each tank car must have a reclosing pressure relief device having a start-to-discharge pressure of 15.51 Bar (225 psig). Title 49 was last amended 2/03/2023. c. Self-propelled vehicles or equipment that also contain an internal combustion engine must be described using the entries Engine, internal combustion, flammable gas powered or Engine, internal combustion, flammable liquid powered or Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. B46 The detachable protective housing for the loading and unloading valves of multi-unit tank car tanks must withstand tank test pressure and must be approved by the Associate Administrator. (a) The Hazardous Materials Table . [Amdt. The standards for transporting a single bulk hazardous material for blasting by cargo tank motor vehicles (CTMV); and. Choosing an item from Lighter refills offered for transportation under this entry may not exceed 4 fluid ounces capacity (7.22 cubic inches) or contain more than 65 grams of fuel. Packagings must be so constructed that explosion is not possible by reason of increased internal pressure. Where different hazardous materials in limited quantities are packed together in the same outer packaging, when a gross mass is indicated Column 4 of 173.27 Table 3, the net quantity of each hazardous material must be shown in addition to the gross mass of the completed package. Quantities of not more than 500 g per package with not less than 10 percent water by mass may also be classed in Division 4.1, provided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). Only Specifications MC 304, MC 307 or DOT 407 cargo tank motor vehicles are authorized for transportation by vessel. 15 This entry applies to Chemical kits and First aid kits containing one or more compatible items of hazardous materials in boxes, cases, etc. The batteries inside the cargo transport unit are not subject to marking or labelling requirements of part 172 subparts D and E of this subchapter. TP6 The tank must be equipped with a pressure release device which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous material to be transported. (7) A code containing the letter T refers to a special provision which applies only to transportation in UN or IM Specification portable tanks. When no IB code is assigned in the 172.101 Table for a specific proper shipping name, or in 173.185 or 173.225(e) Organic Peroxide Table for Type F organic peroxides, use of an IBC or Large Packaging for the material may be authorized when approved by the Associate Administrator. W8 Vessel stowage category for pyrophoric thorium metal or pyrophoric uranium metal is D as defined in 172.101(k)(4). TABLE 2 lists . 349 Mixtures of hypochlorite with an ammonium salt are forbidden for transport. However, sediments remaining in the tank that meet the definition for a hazardous material are subject to the applicable regulations of this subchapter. Column 7 Lists the additional (special) provisions that apply to this material. A212 UN 2031, Nitric acid, other than red fuming, with more than 20% and less than 65% nitric acid intended for use in sterilization devices only, may be transported on passenger aircraft irrespective of the indication of forbidden in columns (9A) of the 172.101 table provided that: a. See UN1210, UN1263, UN1266, UN3066, UN3469, and UN3470. N95 UN1075, Liquefied petroleum gas and UN1978, Propane authorized for transport in DOT 4BA240 cylinders is not subject to the UN identification number and proper shipping name marking or the label requirements of this part subject to the following conditions: a. d. The proper shipping name Printing ink related material may be used for consignments of packages containing Printing ink and Printing ink related material in the same package. PDF 172.101 App A Appendix A to 172.101 - Pipeline and Hazardous This includes vehicles transported in a packaging. W31 Non-bulk packagings must be hermetically sealed. Limited propagation means that if one booster near the center of the package is exploded, the aggregate weight of explosives, excluding ignition and delay charges, in this and all additional boosters in the outside packaging that explode may not exceed 25 g. 116 Fuzes, detonating may be classed in Division 1.4 if the fuzes do not contain more than 25 g of explosive per fuze and are made and packaged so that they will not cause functioning of other fuzes, explosives or other explosive devices if one of the fuzes detonates in a shipping packaging or in adjacent packages. 49 CFR 172.101 - Purpose and use of hazardous materials table. Pressing enter in the search box B78 Tank cars must have a test pressure of 4.14 Bar (60 psig) or greater and conform to Class 103, 104, 105, 109, 111, 112, 114 or 120. N42 1A1 drums made of carbon steel with thickness of body and heads of not less than 1.3 mm (0.050 inch) and with a corrosion-resistant phenolic lining are authorized for stabilized benzyl chloride if tested and certified to the Packing Group I performance level at a specific gravity of not less than 1.8. Transportation of these packages also requires the door of each van trailer to be marked with Warning trailer may contain chemical vapor. With less than 10 percent formaldehyde, are not subject to this subchapter. 137 Cotton, dry; flax, dry; sisal, dry; and tampico fiber, dry are not subject to the requirements of this subchapter when they are baled in accordance with ISO 8115, Cotton Bales - Dimensions and Density (IBR, see 171.7 of this subchapter) to a density of not less than 360 kg/m3 (22.1 lb/ft3) for cotton, 400 kg/m3 (24.97 lb/ft3) for flax, 620 kg/m3 (38.71 lb/ft3) for sisal and 360 kg/m3 (22.1 lb/ft3) for tampico fiber and transported in a freight container or closed transport vehicle. It may be transported on cargo aircraft only with the prior approval of the Associate Administrator. 346 Nitrogen, refrigerated liquid (cryogenic liquid), UN1977 transported in accordance with the requirements for open cryogenic receptacles in 173.320 and this special provision are not subject to any other requirements of this subchapter. In addition to the provisions applicable to the transport of Division 6.1 substances, the provisions of 173.421(c) and 173.443(a) of this subchapter apply. 53 Packages of these materials must bear the subsidiary risk label, EXPLOSIVE, and the subsidiary hazard class/division must be entered in parentheses immediately following the primary hazard class in the shipping description, unless otherwise provided in this subchapter or through an approval issued by the Associate Administrator, or the competent authority of the country of origin. B80 Each cargo tank must have a minimum design pressure of 276 kPa (40 psig). N86 UN pressure receptacles made of aluminum alloy are not authorized. Nickel-carbon asymmetric capacitors containing Class 8 alkaline electrolytes must be transported as UN2795, Batteries, wet, filled with alkali, electric storage. If you have questions or comments regarding a published document please 62 Oxygen generators (see 171.8 of this subchapter) are not authorized for transportation under this entry. UN2258, 1,2-Propylenediamine: In HM-260B, PHMSA removed special provision A6 from column (7) of the . 340 This entry applies only to the vessel transportation of nickel-metal hydride batteries as cargo. The manufacturer must produce technical documentation of the design type, manufacture as well as the tests and their results. A20 Plastic bags as inner receptacles of combination packagings are not authorized for transportation by aircraft. TP3 The maximum degree of filling (in %) for solids transported above their melting points and for elevated temperature liquids shall be determined by the following: Where: df and dr are the mean densities of the liquid at the mean temperature of the liquid during filling and the maximum mean bulk temperature during transport respectively. These packagings are not required to: (1.) The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions. Such packages must be transported on cargo aircraft only. b. 49 CFR -172.101 Hazardous Materials Table info - MaselliWeb (3) Damage to terminals. (c)Column 2: Hazardous materials descriptions and proper shipping names. What is Column 7 of the hazardous materials Table? This is in response to your November 18, 2015 e-mail and subsequent conversations with members of my staff requesting clarification of the Hazardous Materials Regulations (HMR; 49 CFR Parts 171-180) applicable to the selection of a . (9) W codes. Navigate by entering citations or phrases Lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit must use the proper shipping name Lithium batteries installed in cargo transport unit found in the 172.101 Hazardous Materials Table. Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 6.35 mm (0.250 inch) or the thickness required for a tank with a design pressure at least equal to 1.3 times the vapor pressure of the lading at 46 C (115 F). 386 When transported by private motor carrier only, the following corrosive liquids may be packaged in polyethylene bottles with a capacity no greater than 3.785 L (one gallon), further packed inside an open-top, heavy wall, high density polyethylene box (i.e., crate) in a manner that the polyethylene bottles are not subjected to any superimposed weight, and the boxes must be reasonably secured against shifting within the transport vehicle and loaded so as to minimize the possibility of coming in contact with other lading: Compounds, cleaning liquid, NA1760, PG II or III; Corrosive liquid, acidic, inorganic, n.o.s., UN3264, PG II; Corrosive liquid, acidic, organic, n.o.s., UN3265, PG III; Corrosive liquid, basic, inorganic, n.o.s., UN3266, PG II; Hydrochloric acid solution, UN1789, PG II; and. The eCFR is displayed with paragraphs split and indented to follow (2) An indication of compliance with this special provision must be provided by marking each package with the words not restricted or by including the words not restricted on a transport document such as an air waybill accompanying the shipment. 139 Use of the special arrangement proper shipping names for international shipments must be made under an IAEA Certificate of Competent Authority issued by the Associate Administrator in accordance with the requirements in 173.471, 173.472, or 173.473 of this subchapter. When column 7 of the Hazardous Materials Table (49 CFR 172.101) includes a special provision code for an entry in the table, the requirement of that code or codes, there may be several of them is in addition to the generalpackaging requirements of173.24and any other applicable packaging requirements in Part 173. 117 If shipment of the explosive substance is to take place at a time that freezing weather is anticipated, the water contained in the explosive substance must be mixed with denatured alcohol so that freezing will not occur. g. The test results shall be documented, shall be traceable, and shall be made available to a representative of the Department upon request. Shipping papers at all times must reflect a correct current accounting of all cylinders both full and expended. A35 This includes any material which is not covered by any of the other classes but which has an anesthetic, narcotic, noxious or other similar properties such that, in the event of spillage or leakage on an aircraft, extreme annoyance or discomfort could be caused to crew members so as to prevent the correct performance of assigned duties. Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner. A4 Liquids having an inhalation toxicity of Packing Group I are not permitted on aircraft. Tank cars marked HYDROCYANIC ACID prior to October 1, 1991 do not need to be remarked. (b) Preparation for transport. TP45 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. These mixtures may be classified in Division 4.1 when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) and approved by the Associate Administrator. A6 For combination packagings, if plastic inner packagings are used, they must be packed in tightly closed metal receptacles before packing in outer packagings. This particularly applies to corrosivity, permeability, softening, premature aging and embrittlement. 26 This entry does not include ammonium permanganate, the transport of which is prohibited except when approved by the Associate Administrator. R1 A person who offers for transportation tank cars containing sulfur, molten or residue of sulfur, molten may reference the Sulfur Institute's, Molten Sulphur Rail Tank Car Guidance document (see 171.7 of this subchapter) to identify tank cars that may pose a risk in transportation due to the accumulation of formed, solid sulfur on the outside of the tank. Except for transportation by aircraft, in palletized loads, a pallet box or unit load device (e.g. 41 This material at the Packing Group II hazard criteria level may be transported in Large Packagings. Dry batteries specifically covered by another entry in the 172.101 Table must be transported in accordance with the requirements applicable to that entry. (See 173.50 of this subchapter.). Transport in accordance with this special provision must be noted on the shipping paper. B7 Safety relief devices are not authorized on multi-unit tank car tanks. The consignor shall be in possession of a copy of each applicable certificate when packages include fissile material excepted by competent authority approval. If not impact resistant, the outer packaging should not be used as the sole means of protecting the battery terminals from damage or short circuiting. b. A Shipper of a hazardous material is responsible for its classification and packaging prior to offering it for shipment to a Carrier. . A bulk packaging containing sulfur is not subject to the placarding requirements of subpart F of this part, if it is marked with the appropriate identification number as required by subpart D of this part. All successfully conducted tests or reassignment to another compatibility group require the issuance of a new or revised approval by the Associate Administrator prior to transportation on or after the dates specified for each authorized mode of transport in this special provision. Interpretation Response Details. 172 This entry includes alcohol mixtures containing up to 5% petroleum products. B2 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized. B120 The use of flexible bulk containers conforming to the requirements in subpart R and subpart S of part 178 of this subchapter is permitted. 357 A bulk packaging that emits hydrogen sulfide in sufficient concentration that vapors evolved from the crude oil can present an inhalation hazard must be marked as specified in 172.327 of this part. Additionally, the offeror must notify the carrier if the tank pressure rise exceeds 3 psig over any 24-hour period. TP25 Sulphur trioxide 99.95% pure and above may be transported in tanks without an inhibitor provided that it is maintained at a temperature equal to or above 32.5 C (90.5 F). b. Packagings equivalent to DOT 406 cargo tanks are excepted from 178.345-7(d)(5), circumferential reinforcements; 178.345-10, pressure relief; 178.345-11, outlets; 178.345-14, marking, and 178.345-15, certification. individual packaging placed or stacked and secured by strapping, shrink or stretch-wrapping or other suitable means to a pallet). 338 Life Saving appliances, self-inflating transported by motor vehicle only between an U.S. Coast Guard approved inflatable life raft servicing facility and a vessel are only subject to the following requirements: a. IBCs must have a device to allow venting. A portable tank may be offered for transport after the date of expiry of the last lining inspection for a period not to exceed three months for purposes of performing the next required test or inspection, after emptying but before cleaning. N84 The maximum quantity per package is 500 g (1.1 lbs.). The numbers and letters in the special provisions column are referred to in 49 CFR 172.102 with an explanation of their meanings. These provisions apply only to transportation by rail. Choosing an item from 182 Equipment containing only lithium batteries must be classified as either UN 3091 or UN 3481. For transportation by aircraft, as an inner packaging of a combination packaging with a maximum gross mass of 30 kg when packaged as a limited quantity in accordance with 173.27(f).